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CSIR Syllabus

Chemical Sciences Part II Continued

20. Chemistry of Lanthanides and Actinides  :  Spectral and magnetic properties; Use of lanthanide compounds as shift reagents.

21. Organometallic Chemistry of Transition Elements  :  Synthesis, structure and bonding, organometallic reagents in organic synthesis and in homogeneous catalytic reactions  ( hydrogenation, hydroformayalation, isomerisation and polymerization ); pl-acid metal complexes, activation of small molecules by coordination.

22. Topics in Analytical Chemistry  :  Adsorption partition, exclusion electrochromatography, Solvent extraction and ion exchange, methods.  Application of atomic and molecular absorption and emission spectroscopy in quantitative analysis Light scattering techniques including nephelometry and Raman spectroscopy.  Electroalytical techniques: voltammetry, cyclit, voltammetry, polarography, amperometry, coulometry and comductometry ion-elective electrodes.  Annodic stripping voltammetry; TGA, DTA, DSC and online analysors.

23. Bioinorganic Chemistry  :  Metal ions in Biology, Molecular mechanism of ion transport across membranes; ionophores.  Photosynthesis, PSL, PSH; nitrogen fixation, oxygen uptake proteins, cytochromes and ferrodoxins.

24. Aromaticity :  Huckel’s rule and concept of aromaticty (n) annulences and heteroannulenes, fulterenes (C60).

25. Stereochemistry and conformational Analysis :  Nwere method of asymmetric synthesis ( including enzymatic and catalytic nexus ),  enantio and diastereo selective synthesis.  Effects of conformation on reactivity in acyclic compounds and cyclohexanes.

26. Selective Organic Name Reactions :  Favorskli reaction; Stork enamine reaction; Michael addition, Mannich Reaction; Sharpless asymmetric epoxidation; Ene reaction, Barton reaction, Holmann-Loffer-Freytag reaction, Shapiro reaction, Baeyer-Villiger reaction, Chichibabin reaction.

27. Mechanisms of Organic Reactions :  Labelling and Kinetic isotope effects, Hamett equation, ( sigma-rho ) relationship, non-classical carbonium ions, neighbouring group participation.

28. Pericyclic Reactions  :  Selection rules and stereochemistry of electrocyclic reactions, cycloaddition and sigmatropic shifts, Sommelet, Hauser, Cope and Claisen rearrangements.

29. Heterocyclic Chemistry :  Synthesis and reactivity of furan, thiophene, pyrrole, pyridine, quinoline, isoquinoline and indole; Skraup synthesis, Fisher indole synthesis.
30. Reagents in Organic Synthesis  :  Use of the following reagents in organic synthesis and functional group transformations ; Complex metal hybrids, Gilman’s reagent, lithium dimethycuprate, lithium disopropylamide (LDA) dicyclohexylcarbodimide.  1,3 – Dithiane (reactivity umpolung), trimethysilyl iodide, tri-n-butyltin hybride, Woodward and provost hydroxylation, osmium tetroxide, DDQ, selenium dioxide, phase transfer catalysts, crown ethers and Merrified resin, Peterson’s synthesis, Wilkinson’s catalyst, Baker yeast.

31. Chemistry of Natural Products :  Familiarity with methods of structure elucidation and biosynthesis of alkaloids, terponoids, steroids, carbohydrates and proteins.

32. Bio-organic Chemistry :  Elementry structure and function of biopolymers such as proteins and nucleric acids.

33. Photochemistry  :  Cis – trans isomeriation, Paterno – Buchi reaction, Norrish Type I and II reactions, photoreduction of ketones, di-pimethane rearrangement, photochemistry of areanes.

34. Spectroscopy :  Applications of mass,  UV – VIS, IR and NMR spectroscopy for structural elucidation of compound.